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Details of the Faculty or Staff
Name  
Li Chaozhong
Title  
  
Highest Education  
  
Office  
  345 Lingling Road, Shanghai
Phone  
  021-54925160
Zip Code  
  200032
Fax  
  021-54925099
Email  
  clig@sioc.ac.cn

Education and Appointments:

Research Interest:
Free Radical Chemistry
Natural Product Synthesis
Organometallic Chemistry
Public Services:

Honors:
1.中科院“百人计划”(1999)
2.国家杰出青年科学基金(2003)
3.中科院“优秀百人计划”(2003)
4.上海市化学化工学会“吴蕴初奖”提名奖(2004)
5.国家政府特殊津贴(2006)
6.Thieme Chemistry Journal Award(2009)
7.上海市领军人才(2010)
8.Invited Professor, Universite Pierre et Marie Curie(2012)
 
Selected Publication:

1.Chengwei Zhang, Zhaodong Li, Lin Zhu, Limei Yu, Zhentao Wang, and Chaozhong Li*, Silver-Catalyzed Radical Phosphonofluorination of Unactivated Alkenes, J. Am. Chem. Soc. 2013, 135, 14082–14085. 
2.Zhaodong Li, Liyan Song, and Chaozhong Li*, Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media, J. Am. Chem. Soc. 2013, 135, 4640–4643. 
3.Xuesong Liu, Zhentao Wang, Xiaomin Cheng*, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution, J. Am. Chem. Soc. 2012, 134, 14330–14333. 
4.Feng Yin, Zhentao Wang, Zhaodong Li, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution, J. Am. Chem. Soc. 2012, 134, 10401–10404. 
5.Zhentao Wang, Lin Zhu, Feng Yin, Zhongquan Su, Zhaodong Li, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Chlorination of Aliphatic Carboxylic Acids, J. Am. Chem. Soc. 2012, 134, 4258–4263.
6.Deqian Sun, Qiwu Zhao, and Chaozhong Li*, Total Synthesis of (+)-Decursivine, Org. Lett. 2011, 13, 5302–5305.
7.Shunjun Zhuang, Kun Liu*, and Chaozhong Li*, Stereoselective 6-Exo Cyclization of Amidyl Radicals. An Experimental and Theoretical Study, J. Org. Chem. 2011, 76, 8100–8106.
8.Binhua Li, Xiaomin Cheng*, and Chaozhong Li*, Silver-Catalyzed Chlorination of Aromatic Compounds, Chin. J. Chem. 2011, 29, 2809–2812.
9.Liyan Song, Kun Liu, and Chaozhong Li*, Efficient and Regioselective 9-Endo Cyclization of α-Carbamoyl Radicals, Org. Lett. 2011, 13, 3434–3437.
10.Pinhong Chen, Lidong Cao, Wenhai Tian, Xinfeng Wang, and Chaozhong Li*, Total Synthesis and Absolute Configuration Determination of (+)-Subincanadine F, Chem. Commun. 2010, 46, 8436–8438.
11.Lidong Cao and Chaozhong Li*, Synthesis of Oxindoles via Direct Photolysis of N-(2-Bromoaryl)alkanamides, Chin. J. Chem. 2010, 28, 1640–1644.
12.Liqun Chen, Min Shi, and Chaozhong Li*, Synthesis of Functionalized γ-Lactams via Copper-Catalyzed Intramolecular C-Vinylation of Activated Methylene Compounds, Chin. J. Chem. 2010, 28, 1660–1664.
13.Liqun Chen, Yewen Fang, Qiwu Zhao, Min Shi, and Chaozhong Li*, Synthesis of Multisubstituted Furans via Copper-Catalyzed Intramolecular O-Vinylation of Ketones with Vinyl Bromides, Tetrahedron Lett. 2010, 51, 3678–3681.
14.Xinqiang Fang, Kun Liu, and Chaozhong Li*, Efficient Regio- and Stereoselective Formation of Azocan-2-ones via 8-Endo Cyclization of α-Carbamoyl Radicals, J. Am. Chem. Soc. 2010, 132, 2274–2283.
15.Pinhong Chen, Lidong Cao, and Chaozhong Li*, Protecting-Group-Free Total Synthesis of (±)-Subincanadine F, J. Org. Chem. 2009, 74, 7533–7535.
16.Changhui Sun, Yewen Fang, Shuang Li, Yue Zhang, Qiwu Zhao, Shana Zhu, and Chaozhong Li*, Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids, Org. Lett. 2009, 11, 4084–4087.
17.Yi Ju, Feng Liu, and Chaozhong Li*, Palladium-Catalyzed Sequential Cyanation/N-Addition/N-Arylation in One-Pot: Efficient Synthesis of Luotonin A and Its Derivatives, Org. Lett. 2009, 11, 3582–3585.
18.Feng Liu and Chaozhong Li*, Intramolecular Formal [4+2] Cycloaddition of Nitriles with Amides Triggered by TMSOTf/Et3N: Highly Efficient Construction of Pyrrolo[1,2-a]pyrimidin-4(6H)-ones, J. Org. Chem. 2009, 74, 5699–5702.
19.Qiwu Zhao, Ling Li, Yewen Fang, Deqian Sun, and Chaozhong Li*, “Ligand-Free” CuI-Catalyzed Highly Efficient Intramolecular S-Vinylation of Thiol with Vinyl Chlorides and Bromides, J. Org. Chem. 2009, 74, 459462.
20.Lidong Cao and Chaozhong Li*, p-MeOC6H4N2+BF4-/TiCl3: A Novel Initiator for Halogen Atom-Transfer Radical Reactions in Aqueous Media, Tetrahedron Lett. 2008, 49, 7380–7382.
21.Liqun Chen, Min Shi, and Chaozhong Li*, Cu(I)-Catalyzed Intramolecular C–C Coupling of Activated Methylene Compounds with Vinyl Halides: Efficient Synthesis of Functionalized Alkylidenecyclobutanes, Org. Lett. 2008, 10, 52855288.
22.Hongjian Lu, Xinting Yuan, Shana Zhu, Changhui Sun, and Chaozhong Li*, Copper-Catalyzed Intramolecular N-Vinylation of Sulfonamides: General and Efficient Synthesis of Heterocyclic Enamines and Macrolactams, J. Org. Chem. 2008, 73, 86658668.
23.Qiwu Zhao and Chaozhong Li*, Preference of β-Lactam Formation in Cu(I)-Catalyzed Intramolecular Coupling of Amides with Vinyl Bromides, Org. Lett. 2008, 10, 40374040.
24.Xinting Yuan, Kun Liu and Chaozhong Li*, Development of Highly Regioselective Amidyl Radical Cyclization Based on Lone Pair – Lone Pair Repulsion, J. Org. Chem. 2008, 73, 61666171.
25.Pinhong Chen, Junhua Wang*, Kun Liu and Chaozhong Li*, Synthesis and Structural Revision of (±)Laurentristich-4-ol, J. Org. Chem. 2008, 73, 339341.
26.Feng Liu, Kun Liu, Xinting Yuan and Chaozhong Li*, 5-Exo versus 6-Endo Cyclization of Primary Aminyl Radicals: An Experimental and Theoretical Investigation, J. Org. Chem. 2007, 72, 10231–10234.
27.Xinqiang Fang, You-Cheng Liu*, and Chaozhong Li*, 9-Phenyl-10-methylacridinium: A Highly Efficient and Reusable Organocatalyst for Mild Aromatization of 1,4-Dihydropyridines by Molecular Oxygen, J. Org. Chem. 2007, 72, 86088610.
28.Tianshun Hu, Kun Liu, Meihua Shen, Xinting Yuan, Yu Tang and Chaozhong Li*, O-Attack versus N-Attack: Electrophilic Halocyclization of Unsaturated Amides with Vinylic Halogen Substitution, J. Org. Chem. 2007, 72, 8555–8558.
29.Yewen Fang and Chaozhong Li*, Preference of 4-Exo Ring Closure in Copper-Catalyzed Intramolecular Coupling of Vinyl Bromides with Alcohols, J. Am. Chem. Soc. 2007, 129, 80928093.
30.Yuanjia Pan, Hongjian Lu, Yewen Fang, Xinqiang Fang, Liqun Chen, Junlu Qian, Junhua Wang and Chaozhong Li*, Synthesis of Pyrroles via Copper-Catalyzed Coupling of Amines with Bromoenones, Synthesis 2007, 12421246.
31.Hongjian Lu, Qian Chen and Chaozhong Li*, Control of the Regioselectivity of Sulfonamidyl Radical Cyclization by Vinylic Halogen Substitution, J. Org. Chem. 2007, 72, 2564–2569.
32.Qian Chen and Chaozhong Li*, Activation of the Vinylic C-Cl Bond by Complexation of Fe(CO)3: Palladium-Catalyzed Coupling Reactions of (h4-Chlorodiene)tricarbonyliron Complexes, Organometallics 2007, 26, 223–229.
33.Hongjian Lu and Chaozhong Li*, General and Highly Efficient Synthesis of 2-Alkylideneazetidines and b-Lactams via Copper-Catalyzed Intramolecular N-Vinylation, Org. Lett. 2006, 8, 5365–5367.
34.Yewen Fang and Chaozhong Li*, O-Arylation versus C-Arylation: Copper-Catalyzed Intramolecular Coupling of Aryl Bromides with 1,3-Dicarbonyls, J. Org. Chem. 2006, 71, 6427–6431.
35.Tianshun Hu, Meihua Shen, Qian Chen and Chaozhong Li*, Pushing Radical Cyclization from Regioselective to Regiospecific: Cyclization of Amidyl Radicals Controlled by Vinylic Halogen Substitution, Org. Lett. 2006, 8, 2647–2650.
36.Yu Tang and Chaozhong Li*, Facile 5-Endo Electrophilic Cyclization of Unsaturated Amides with tBuOCl/I2, Tetrahedron Lett. 2006, 47, 3823–3825.
37.Hechun Lin, Qian Chen, Lidong Cao, Li Yang, Yun-Dong Wu* and Chaozhong Li*, Effect of M(CO)3 (M = Cr, Mn+) on Aromatic C-Cl BDE in (h6-ArCl)M(CO)3 Complexes, J. Org. Chem. 2006, 71, 33283331.
38.Lidong Cao, Meihua Shen and Chaozhong Li*, Indium-Mediated Alkyl Addition to (h6-Arene)tricarbonylmanganese Complexes in Aqueous Media, Organometallics 2005, 24, 5983–5988.
39.Hongjian Lu and Chaozhong Li*, Facile Cyclization of Amidyl Radicals Generated from N-Acyltriazenes, Tetrahedron Lett. 2005, 46, 59835985.
40.Yewen Fang and Chaozhong Li*, CuI-Catalyzed Intramolecular O-Vinylation of Carbonyl Compounds, Chem. Commun. 2005, 35743576.
41.Tianshun Hu and Chaozhong Li*, Synthesis of Lactams via Copper-Catalyzed Intramolecular Vinylation of Amides, Org. Lett. 2005, 7, 20352038.
42.Qian Chen, Meihua Shen, Yu Tang and Chaozhong Li*, Cyclization or Hydrogen Migration: Theoretical Study and Experimental Evidence on the Reactivities of Unsaturated Amidyl Radicals, Org. Lett. 2005, 7, 16251627.
43.Li Liu, Qian Chen, Yun-Dong Wu* and Chaozhong Li*, 8-Endo versus 7-Exo Cyclization of a-Carbamoyl Radicals. A Combination of Experimental and Theoretical Studies, J. Org. Chem. 2005, 70, 15391544.
44.Xuefeng Jiang, Meihua Shen, Yu Tang and Chaozhong Li*, Chemoselective Monobromination of Alkanes Promoted by Unactivated MnO2, Tetrahedron Lett. 2005, 46, 487–489.
45.Meihua Shen and Chaozhong Li*, Asymmetric Iodolactamization Induced by Chiral Oxazolidine Auxiliary, J. Org. Chem. 2004, 69, 7906–7909.
46.Yu Tang and Chaozhong Li*, Facile 5-Endo Amidyl Radical Cyclization Promoted by Vinylic Iodine Substitution, Org. Lett. 2004, 6, 3229–3231.
47.Hui Yu and Chaozhong Li*, Self-Protection: The Advantage of Radical Oligomeric Mixtures in Organic Synthesis, J. Org. Chem. 2004, 69, 142–145.
48.Tao Wu, Hui Yu and Chaozhong Li*, Trifluoroacetic Acid: A Unique Solvent for Atom Transfer Radical Cyclization Reactions, Arkivoc 2004, (ix), 60–65.
49.Li Liu, Xing Wang, Chaozhong Li*, Deoligomerization: A New Route to Lactams from Unsaturated Amides via Radical Oligomerization, Org. Lett. 2003, 5, 361–363.
50.Hechun Lin, Meihua Shen, Li Yang* and Chaozhong Li*, Progress on Radical Reactions of Arene Metal Complexes, Chin. J. Org. Chem. 2003, 23, 944–949.
51.Hechun Lin, Li Yang* and Chaozhong Li*, Comparison of (h6-Fluoroarene)tricarbonylchromium Complexes with Their Chloro-analogs in Radical Aromatic Substitution, Chin. J. Chem. 2003, 21, 797–800.
52.Xingang Fang, Hairong Xia, Hui Yu, Xicheng Dong, Minbo Chen, Quanrui Wang, Fenggang Tao and Chaozhong Li*, On the 6-Exo Atom Transfer Radical Cyclization Reactions of 3-Butenyl 2-Iodoalkanoates, J. Org. Chem. 2002, 67, 8481–8488.
53.Hechun Lin, Li Yang and Chaozhong Li*, Radical Aromatic Substitutions on (h6-Chloroarene)-tricarbonylchromium Complexes, Organometallics 2002, 21, 3848–3849.
54.Hui Yu, Tao Wu and Chaozhong Li*, Converting Radical Oligomers to a Single Product, J. Am. Chem. Soc. 2002, 124, 10302–10303.
55.Junhua Wang and Chaozhong Li*, Investigation of Bis(tributyltin)-Initiated Free Radical Cyclization Reactions of 4-Pentenyl Iodoacetates, J. Org. Chem. 2002, 67, 1271–1276.
56.Hechun Lin, Hongjun Zhang, Li Yang and Chaozhong Li*, First Alkyl Radical Additions to (h6-Arene)tricarbonylmanganese Complexes, Org. Lett. 2002, 4, 823–825.


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