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Title: Ring-Opening Polymerization of L-lactides Catalyzed by Zinc-Sodium/Lithium Heterobimetallic Complexes in Presence of Water
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Two heterobimetallic complexes, [(TBBP)2Zn][(Na)2(THF)4] (3) and [(TBBP)2Zn][(Li)2(THF)4] (4) can initiate the ring-opening polymerization of L-lactide in a controlled fashion. Complex 3 can initiate the ring-opening polymerization of unsublimed L-lactide under moist conditions even in the presence of H2O, to yield a high conversion and with controllable molecular weight.

Contact the author: Lei Wang1, Xiaobo Pan2, Lihui Yao1, Ning Tang1, Jincai Wu1
Page number: 632-636
Issue: 5
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PubYear: 2011
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Unit code: 153937
Publication name: J.Inorg.Chem.
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