| 承担科研项目: |
负责承担国家自然科学基金委面上项目:
不对称羰化合成手性功能高分子聚酮(2005.01-2007.12),
不对称酰胺羰化合成手性N-酰基-α-氨基酸(2008.01-2010.12),
α-烯烃不对称三羰基化反应研究(2011.1-2013.12);
国家自然科学基金委化学部主任专项基金:
离子液体中的对映选择性交替共聚反应(2004.01-2004.12),
钯催化的不对称酰胺羰化反应研究(2007.01-2007.12);
中科院知识创新工程重要方向项目:
“离子液体应用研究”子课题“离子液体中的不对称催化反应研究”(No.KGXCX2-SW-211),(2004.01-2006.12);
甘肃省科技支撑计划-社会发展计划项目:
造纸废液中木质素用于化学固沙剂的制备研究( 2007.07-2009.07);
中科院“西部之光”人才培养计划资助项目:
造纸废液中木质素用于化学固沙剂的制备研究(2009.12-2012.12)。
参加国家自然科学基金重点项目:均相络合催化的应用基础研究(2000-2003)。 |
| 代表论著: |
[1] Y. M. Cui, L. L. Wang,* et. al.,“A highly efficient chiral-bridged diphosphine ligand modified cationic Palladium (II) catalyst system for asymmetric alternating copolymerization of propene and carbon monoxide”, Synlett, 2009 (16), 2696-2700.
[2] Q. L. Zhao, M. Yang, L. L. Wang,* “Efficient ligand-free, palladium catalyzed amidocarbonylation in ionic liquids: facile synthesis of N-acyl-a-arylglycines”, Synthetic Communications, 2008, 38, 4460. [3] Q. L. Zhao, L. L. Wang,* Albert S. C. Chan, “Cu-catalyzed enantioselective conjugate addition of diethyzinc to cyclic enones with chiral phosphite ligands derived from 1,2:5,6-di-O-cyclohexylidene-D-mannitol”, Tetrahedron: Asymmetry, 2007, 18, 1899. [4] H. J. Wang, L. L. Wang,* Albert S. C. Chan,“Pd-catalyzed asymmetric alternating copolymerization of propene with carbon monoxide using ionic liquids”, Tetrahedron: Asymmetry, 2006,17, 7. [5] L. L. Wang, R. W. Guo, Albert S. C. Chan,“Rhodium catalyzed asymmetric hydroformylation of vinylarenes with novel chiral P,N-ligands derived from 1,2:5,6-di-O-cyclohexylidene-D-mannitool”, Tetrahedron: Asymmetry, 2005, 16, 3198. [6] L. L. Wang, Z. Y. Zhou, Albert S. C. Chan, “Synthesis of new chiral aryl diphosphite ligands derived from pyranoside backbone of monosacharides and their application in copper-catalyzed asymmetric conjugate addition of diethylzinc to cyclic enones”, Adv. Synth. Catal., 2004, 346, 947. [7] L. L. Wang, Albert S. C. Chan, X. L. Hou, and L. X. Dai, “Asymmetric hydroesterification of styrene using catalysts with planar-chiral ferrocene oxazoline ligands”, Tetrahedron: Asymmetry, 2003, 14, 2291. [8] 王来来,王海君,不对称羰化法合成手性功能高分子聚酮的方法,专利号:ZL200510048322.4 [9] 王来来,董治宝,赵水侠,木质素磺酸盐接枝共聚物化学固沙剂制备方法,专利号:ZL200710188572.7 |